全文获取类型
收费全文 | 14586篇 |
免费 | 2840篇 |
国内免费 | 1465篇 |
专业分类
化学 | 3027篇 |
晶体学 | 182篇 |
力学 | 2658篇 |
综合类 | 189篇 |
数学 | 2537篇 |
物理学 | 10298篇 |
出版年
2024年 | 16篇 |
2023年 | 147篇 |
2022年 | 266篇 |
2021年 | 347篇 |
2020年 | 446篇 |
2019年 | 350篇 |
2018年 | 366篇 |
2017年 | 478篇 |
2016年 | 581篇 |
2015年 | 518篇 |
2014年 | 807篇 |
2013年 | 1149篇 |
2012年 | 860篇 |
2011年 | 974篇 |
2010年 | 890篇 |
2009年 | 944篇 |
2008年 | 955篇 |
2007年 | 911篇 |
2006年 | 919篇 |
2005年 | 818篇 |
2004年 | 871篇 |
2003年 | 710篇 |
2002年 | 657篇 |
2001年 | 524篇 |
2000年 | 512篇 |
1999年 | 446篇 |
1998年 | 404篇 |
1997年 | 332篇 |
1996年 | 268篇 |
1995年 | 209篇 |
1994年 | 184篇 |
1993年 | 146篇 |
1992年 | 136篇 |
1991年 | 125篇 |
1990年 | 93篇 |
1989年 | 100篇 |
1988年 | 73篇 |
1987年 | 57篇 |
1986年 | 64篇 |
1985年 | 49篇 |
1984年 | 31篇 |
1983年 | 16篇 |
1982年 | 26篇 |
1981年 | 25篇 |
1980年 | 19篇 |
1979年 | 16篇 |
1978年 | 13篇 |
1977年 | 10篇 |
1976年 | 7篇 |
1957年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 718 毫秒
961.
从洛仑兹力方程的旋量形式出发,讨论了电磁场中电荷运动的轴向电场和轴向磁场问题以及平面波的脉冲和Larmor功率。这些问题是研究自共振激光加速器的基础。From the spinorial form of the Lorentz force equation, the problems about axial electric field and axial magnetic field of charge motion in electromagnetic fields, as well as plane wave pulse and Larmor power have been discussed in this paper. These problems are the foundation of studying the autoresonance laser accelerator (ALA). 相似文献
962.
采用密度泛函(DFT)方法B3P86在6 311++G(d,p)基组水平上优化得到了分子轴方向不同电偶极 场(-0.04~0.04a.u.)作用下,二甲基硅酮的基态电子状态、几何结构、电偶极矩和分子总能量.在优化构型下 用同样的基组采用杂化CIS DFT方法(CIS B3P86)研究了同样外电场条件下对二甲基硅酮的激发能和振子强度 的影响.计算结果表明,分子几何构型与电场大小和方向呈现强烈的依赖,正向电场下基态偶极矩随电场强度线 性增加,分子总能量降低,当反向电场大于0.03a.u.时,偶极距方向改变,总能量增加;激发能随电场增加急剧减 小,且对电场方向的依赖呈现出不对称性,满足Grozema关系.电场对振子强度的影响比较复杂,但仍满足跃迁选 择定则. 相似文献
963.
Victor V. Terskikh Stephen J. Lang Peter G. Gordon Gary D. Enright John A. Ripmeester 《Magnetic resonance in chemistry : MRC》2009,47(5):398-406
This work reports significantly improved spectral resolution of 13C CP MAS NMR spectra of chlorinated, brominated and iodinated solid organic compounds when such spectra are recorded at ultrahigh magnetic field strengths. The cause of this is the residual dipolar coupling between carbon atoms and quadrupolar halogen nuclides (chlorine‐35/37, bromine‐79/81 or iodine‐127), an effect inversely proportional to the magnetic field strength which declines in importance markedly at 21.1 T as compared to lower fields. In favorable cases, the fine structure observed can be used for spectral assignment, e.g. for Cl‐substituted aromatics where the substituted carbon as well as the ortho‐carbons show distinct doublets. The experimental results presented are supported by theoretical modeling and calculations. The improved spectral resolution in the studied systems and similar halogenated materials will be of particular interest and importance for polymorph identification, drug discovery and quality control in the pharmaceutical industry. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
964.
Woo‐Hyung Lee Hoyoul Kong Se‐Young Oh Hong‐Ku Shim In‐Nam Kang 《Journal of polymer science. Part A, Polymer chemistry》2009,47(1):111-120
A series of modified thiophene groups containing PPV‐based semiconducting materials, poly[(2,5‐bis(octyloxy)‐1,4‐phenylenevinylene)‐alt‐(2,2′bithienylenevinylene)] ( PPBT ), poly[(2,5‐bis(octyloxy)‐1,4‐phenylenevinylene)‐alt‐(5,5‐thiostilylenevinylene)] ( PPTVT ), have been synthesized through a Horner coupling reaction. From the FTIR and 1H NMR spectroscopy, the configuration of the vinylene groups in the polymers was all trans (E) geometry. The weight‐average molecular weights (Mw) of PPBT and PPTVT were found to be 11,700 and 11,800, with polydispersity indices of 2.51 and 2.53, respectively. PPBT and PPTVT thin films exhibit UV–visible absorption maxima at 538 and 558 nm, respectively, and the strong absorption shoulder peaks at 578 and 602 nm, respectively. Solution processed field‐effect transistors (FET) fabricated using all the polymers showed p‐type OTFT characteristics. The field‐effect mobility of the PPTVT was obtained up to 2.3 × 10?3 cm2 V?1 s?1, an on/off ratio of 1.0 × 105 with ambient air stability. Studies of the atomic force microscopy (AFM) and X‐ray diffraction (XRD) analysis of the polymer thin films revealed that all the polymers were amorphous structure. The greater planarity and rigidity of PPTVT compared to PPBT results in elongation of conjugation length and better π–π stacking of polymer chains in amorphous region, which leads to improved FET performance. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 111–120, 2009 相似文献
965.
Houxiang Sean Tang Theresa J. Hermel‐Davidock Stephen F. Hahn Dan J. Murray Robert C. Cieslinski Nikhil E. Verghese Ha Q. Pham 《Journal of Polymer Science.Polymer Physics》2009,47(4):393-406
Microdeformation behavior in nanostructured block copolymer‐toughened epoxy resins, or templated epoxy thermosets, was studied using an in situ tensile deformation technique performed directly in a transmission electron microscope. The observed microdeformation modes were found to correlate well with the macroscopic mechanical properties of the materials. In the order of decreasing macroscopic fracture toughness, the microdeformation modes were observed to change from large uniform plastic deformation over an extensive area, to localized plastic deformation bands, to little plastic deformation observed in the most brittle material. A similar trend was also observed when samples of the same material were tested at different temperatures, reflecting changes in the deformation mechanism as a function of temperature. Structural defects were observed in nanotoughening phases when plastic deformation was observed. The implication of the observed microdeformation modes to the macroscopic toughening mechanisms is discussed in the context of the micromorphology of the nanometer sized toughening phases and parameters of the epoxy matrix chemistry such as bromination, molecular weight, and interfacial miscibility. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 393–406, 2009 相似文献
966.
多光子J-C模型的场熵的演化 总被引:5,自引:0,他引:5
研究了一个二能级原子与相干光场多光子相互作用下场熵演化的动力学特性 相似文献
967.
A. G. Aleksandrov 《Functional Analysis and Its Applications》2005,39(4):245-255
We introduce the notion of logarithmic index of a vector field on a hypersurface and prove that the homological index can be expressed via the logarithmic index. Then both invariants are described in terms of logarithmic differential forms for Saito free divisors, which are hypersurfaces with nonisolated singularities, and all contracting homology groups of the complex of regular holomorphic forms on such a hypersurface are computed. In conclusion, we consider the case of normal hypersurfaces, including the case of an isolated singularity, and describe the contracting homology of the complex of regular meromorphic forms with the help of the residue of logarithmic forms. 相似文献
968.
Marzena Ciemala Kazimierz Szymiczek 《Proceedings of the American Mathematical Society》2005,133(9):2519-2523
We prove that the kernel of the ring homomorphism between the Witt ring of any order of a global field and the Witt ring of the field is a nilideal.
969.
970.
The study of rotor–fuselage interactional aerodynamics is central to the design and performance analysis of helicopters. However, regardless of its significance, rotor–fuselage aerodynamics has so far been addressed by very few authors. This is mainly due to the difficulties associated with both experimental and computational techniques when such complex configurations, rich in flow physics, are considered. In view of the above, the objective of this study is to develop computational tools suitable for rotor–fuselage engineering analysis based on computational fluid dynamics (CFD). To account for the relative motion between the fuselage and the rotor blades, the concept of sliding meshes is introduced. A sliding surface forms a boundary between a CFD mesh around the fuselage and a rotor‐fixed CFD mesh which rotates to account for the movement of the rotor. The sliding surface allows communication between meshes. Meshes adjacent to the sliding surface do not necessarily have matching nodes or even the same number of cell faces. This poses a problem of interpolation, which should not introduce numerical artefacts in the solution and should have minimal effects on the overall solution quality. As an additional objective, the employed sliding mesh algorithms should have small CPU overhead. The sliding mesh methods developed for this work are demonstrated for both simple and complex cases with emphasis placed on the presentation of the inner workings of the developed algorithms. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献